Studi Eksperimen Dan Komputasi Senyawa Organik Sebagai Inhibitor Korosi : A Review
Keywords:
Corrosion inhibitors, DFT, MC, Plant Extracts, Computing
Abstract
Modeling organic compounds with computational software is an option for researchers before conducting experiments in the laboratory. This helps to understand the mechanism of corrosion inhibition of metals on an atomic and molecular scale. Some of the common computational techniques used are DFT theory, MD and Monte carlo simulations. According to the literature, choosing organic compounds through modeling helps researchers determine the efficiency of the right inhibitor, saving time and money. Another advantage of this computational model is that it can easily determine the active sites/adsorption sites and the orientation of organic compounds. This review discusses indicators of corrosion inhibition contained in several computational models. The mechanism of corrosion inhibition by natural compounds and the types of inhibition of compounds are also discussed through polarization potentiodynamics.
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References
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[25] A. M. Abdel-Gaber, A. Ezzat, and M. E. Mohamed, “Fenugreek seed and cape gooseberry leaf extracts as green corrosion inhibitors for steel in the phosphoric acid industry,” Sci. Rep., vol. 12, no. 1, p. 22251, 2022, doi: 10.1038/s41598-022-26757-z.
[2] Z. Shang and J. Zhu, “Overview on plant extracts as green corrosion inhibitors in the oil and gas fields,” J. Mater. Res. Technol., vol. 15, pp. 5078–5094, 2021, doi: 10.1016/j.jmrt.2021.10.095.
[3] J. U. Ani, I. O. Obi, K. G. Akpomie, S. I. Eze, and G. Nwatu, “Corrosion Inhibition Studies of Metals in Acid Media by Fibrous Plant Biomass Extracts and Density Functional Theory: A Mini-Review,” J. Nat. Fibers, vol. 0, no. 0, pp. 1–11, Nov. 2020, doi: 10.1080/15440478.2020.1818345.
[4] A. Pal and C. Das, “Novel use of kitchen waste: protection of boiler quality steel from corrosion in acidic media using onion waste,” Chem. Pap., vol. 77, no. 2, pp. 1107–1127, 2023, doi: 10.1007/s11696-022-02549-7.
[5] N. Kedimar, P. Rao, and S. A. Rao, “Ionic liquid as an effective green inhibitor for acid corrosion of aluminum composite: experimental and theoretical considerations,” J. Appl. Electrochem., vol. 53, no. 7, pp. 1473–1489, 2023, doi: 10.1007/s10800-023-01854-7.
[6] A. El-Asri et al., “Carissa macrocarpa extract (ECM) as a new efficient and ecologically friendly corrosion inhibitor for copper in nitric acid: Experimental and theoretical approach,” J. Taiwan Inst. Chem. Eng., vol. 142, no. November 2022, 2023, doi: 10.1016/j.jtice.2022.104633.
[7] S. Hadisaputra, A. A. Purwoko, A. Hakim, N. Prasetyo, and S. Hamdiani, “Corrosion Inhibition Properties of Phenyl Phthalimide Derivatives against Carbon Steel in the Acidic Medium : DFT , MP2 , and Monte Carlo Simulation Studies,” 2022, doi: 10.1021/acsomega.2c03091.
[8] J. Kaur, N. Daksh, and A. Saxena, “Corrosion Inhibition Applications of Natural and Eco ‑ Friendly Corrosion Inhibitors on Steel in the Acidic Environment : An Overview,” pp. 57–74, 2022.
[9] M. H. Abdellattif, S. H. Alrefaee, O. Dagdag, C. Verma, and M. A. Quraishi, “Calotropis procera extract as an environmental friendly corrosion Inhibitor: Computational demonstrations,” J. Mol. Liq., vol. 337, no. 2, p. 116954, 2021, doi: 10.1016/j.molliq.2021.116954.
[10] L. Chen and D. Lu, “Organic Compounds as Corrosion Inhibitors for Carbon Steel in HCl Solution : A Comprehensive Review,” pp. 1–59, 2023.
[11] M. P. Asfia, M. Rezaei, and G. Bahlakeh, “ur l P re,” J. Mol. Liq., p. 113679, 2020, doi: 10.1016/j.molliq.2020.113679.
[12] A. Kumar and C. Verma, “Coco Monoethanolamide Surfactant as a Sustainable Corrosion Inhibitor for Mild Steel : Theoretical and Experimental Investigations,” 2023.
[13] N. D. Mu’azu et al., “Inhibition of low carbon steel corrosion by a cationic gemini surfactant in 10wt.% H2SO4 and 15wt.% HCl under static condition and hydrodynamic flow,” South African J. Chem. Eng., vol. 43, no. August 2022, pp. 232–244, 2023, doi: 10.1016/j.sajce.2022.10.006.
[14] F. Simescu-Lazar et al., “Thymus satureoides Oil as Green Corrosion Inhibitor for 316L Stainless Steel in 3% NaCl: Experimental and Theoretical Studies,” Lubricants, vol. 11, no. 2, 2023, doi: 10.3390/lubricants11020056.
[15] D. S. Chauhan, C. Verma, and M. A. Quraishi, “Molecular structural aspects of organic corrosion inhibitors: Experimental and computational insights,” J. Mol. Struct., vol. 1227, no. xxxx, p. 129374, 2021, doi: 10.1016/j.molstruc.2020.129374.
[16] M. Rbaa, F. Benhiba, P. Dohare, and L. Lakhrissi, “Synthesis of new epoxy glucose derivatives as a non-toxic corrosion inhibitors for carbon steel in molar HCl : Experimental , DFT and MD simulation,” vol. 27, 2020, doi: 10.1016/j.cdc.2020.100394.
[17] M. En-nylly, S. Skal, Y. El, H. Lgaz, and R. J. Adnin, “Performance evaluation and assessment of the corrosion inhibition mechanism of carbon steel in HCl medium by a new hydrazone compound : Insights from experimental , DFT and first-principles DFT simulations,” Arab. J. Chem., vol. 16, no. 6, p. 104711, 2023, doi: 10.1016/j.arabjc.2023.104711.
[18] Z. Akounach et al., “Contribution to the corrosion inhibition of aluminum in 1 M HCl by Pimpinella Anisum extract . Experimental and theoretical studies ( DFT , MC , and MD ),” no. 1, pp. 402–424, 2022, doi: 10.17675/2305-6894-2022-11-1-24.
[19] V. Vorobyova, O. Sikorsky, M. Skiba, and G. Vasyliev, “Quebracho tannin as corrosion inhibitor in neutral media and novel rust conversion agent for enhanced corrosion protection,” South African J. Chem. Eng., vol. 44, no. September 2022, pp. 68–80, 2023, doi: 10.1016/j.sajce.2023.01.003.
[20] S. Cherrad et al., “Cupressus arizonica fruit essential oil : A novel green inhibitor for acid corrosion of carbon steel,” Arab. J. Chem., vol. 15, no. 6, p. 103849, 2022, doi: 10.1016/j.arabjc.2022.103849.
[21] C. . Nwachukwu, I. M. Dagwa, and B. I. Ugheoke, “Optimization of Blended Guava and Fluted Pumpkin Leaves extract as corrosion inhibitor of mild steel in 0.5 m hydrochloric acid,” Niger. J. Technol., vol. 40, no. 3, pp. 393–403, 2021, doi: 10.4314/njt.v40i3.6.
[22] R. T. Loto, “granatum , and camellia sinensis extracts on plain carbon steel,” Cogent Eng., vol. 7, pp. 1–16, 2020, doi: https://doi.org/10.1080/23311916.2020.1798579.
[23] N. K. Brixi, R. Cherif, A. Bezzar, L. Sail, and A. Aït-Mokhtar, “Effectiveness of henna leaves extract and its derivatives as green corrosion inhibitors of reinforcement steel exposed to chlorides,” Eur. J. Environ. Civ. Eng., vol. 26, no. 12, pp. 5912–5930, 2022, doi: 10.1080/19648189.2021.1925159.
[24] V. Pourzarghan and B. Fazeli-Nasab, “The use of Robinia pseudoacacia L fruit extract as a green corrosion inhibitor in the protection of copper-based objects,” Herit. Sci., vol. 9, no. 1, pp. 1–14, 2021, doi: 10.1186/s40494-021-00545-w.
[25] A. M. Abdel-Gaber, A. Ezzat, and M. E. Mohamed, “Fenugreek seed and cape gooseberry leaf extracts as green corrosion inhibitors for steel in the phosphoric acid industry,” Sci. Rep., vol. 12, no. 1, p. 22251, 2022, doi: 10.1038/s41598-022-26757-z.
Published
2023-07-30
How to Cite
Maidawati, M. (2023). Studi Eksperimen Dan Komputasi Senyawa Organik Sebagai Inhibitor Korosi : A Review. Jurnal Penelitian Dan Pengkajian Ilmiah Eksakta, 2(2), 148-153. https://doi.org/10.47233/jppie.v2i2.1030
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Articles
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